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Article
Publication date: 17 April 2024

Quratulain Mohtashim, Salma Farooq and Fareha Asim

The application of indigo dyes in the denim industries has been criticised due to the introduction of non-renewable oxidation products into the environment. Previous studies have…

Abstract

Purpose

The application of indigo dyes in the denim industries has been criticised due to the introduction of non-renewable oxidation products into the environment. Previous studies have investigated that reducing sugars can be used as green alternatives to sodium dithionite in the indigo dyeing of cotton fabric owing to their reduced and stable redox potential in the dye bath. The purpose of this study was to dye denim cotton fabric with indigo dye using various reducing sugars and alkalis. The use of sucrose and potassium hydroxide (KOH) for indigo dyeing has been explored for the first time.

Design/methodology/approach

A mixed factorial design with four variables including alkali, pH, number of dips and type of reducing sugar at different levels was studied to identify a significant correlation between the effect of these variables on the colour strength and fastness properties of the dyeings.

Findings

Investigations were made to examine the significant factors and interactions of the selected responses in the eco-friendly dyeing method. This process has the potential to reduce the load of sulphite and sulphate generated in the dyebath due to the use of a conventional reducing agent, sodium dithionite. The colour strength of the dyeing reduced with fructose was found to be better than other reducing sugars and significantly influenced by the number of dips, pH levels and the interaction between pH and reducing sugars. Using fructose for indigo dyeing with two dips at a pH of 11.5, using KOH as an alkali, results in higher colour strength values. The fastness properties of the indigo-dyed sample with reducing sugars ranging from fair to good or good to excellent. Specifically, colour change receives a rating of grey scale 3–4, staining 4–5, dry rubbing 4 and light fastness 3–4. These assessments hold true across various factors such as the type of reducing sugar, alkali, pH and the number of dips. The optimised parameters leading to improved colour strength and fastness properties are also discussed.

Originality/value

This dyeing technique is novel and a green alternative to dithionite denim dyeing. This process is found to be useful for indigo dyeing of denim fabric leading to reduced and stable redox potential in the dyebath and acceptable colour strength of the dyed fabric.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 7 June 2022

Quratulain Mohtashim, Fareha Asim and Salma Farooq

The application of synthetic dyestuffs in the dyeing and printing industries has been criticized because of the introduction of contaminants into the environment. With time, the…

Abstract

Purpose

The application of synthetic dyestuffs in the dyeing and printing industries has been criticized because of the introduction of contaminants into the environment. With time, the increasing international awareness of environment and ecology preservation has led to the industry’s attention towards natural dyes and their efficient usage compared to synthetic counterparts. Because the need for “Green” goods and services are rising public awareness, this paper aims to use a banana bio-resource waste to dye cotton fabric.

Design/methodology/approach

Factorial design with three variables, including parts of a banana plant, combination of alkalis and application temperature at three different levels, was studied to identify a significant correlation between the effect of these variables on the colour strength and fastnesses of the dyed cotton fabrics.

Findings

Dyeing samples achieved with various parts of banana are found to offer significant colour strength and a good wash and rub fastness. Experimental design analysis helped to formulate a standard workable dyeing recipe with the minimum use of resources exhibiting reasonably good wash and rub fastness.

Originality/value

This dyeing technique is novel and can be found useful for partially replacing synthetic dyes with natural colourants possessing good washing and rubbing fastness.

Details

Pigment & Resin Technology, vol. 52 no. 6
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 2 June 2020

Quratulain Mohtashim, Muriel Rigout and Sheraz Hussain Siddique

Sulphur dyes are the most highly consumed colourants for cellulosic substrates owing to their reasonable cost and acceptable fastness. However, the use of noxious conventional…

Abstract

Purpose

Sulphur dyes are the most highly consumed colourants for cellulosic substrates owing to their reasonable cost and acceptable fastness. However, the use of noxious conventional reducing agent, sodium sulphide and impaired wash fastness against oxidative bleaching is gradually decreasing the market of these dyes. As the need for “Green” goods and services is raising public awareness, this paper aims to use a glucose-based biodegradable reducing agent in place of sodium sulphide to dye cotton fabrics with a range of commercial sulphur dyes. The study also proposes an aftertreatment method to improve the fastness properties of the dyeing.

Design/methodology/approach

The paper investigated the impact of a newly developed aftertreatment method on the fastness properties of dyeing. This involved the sequential application of a cationic fixing agent (Tinofix ECO) and tannin (Bayprotect CL) on the coloured fabrics and subsequent evaluation of colour strength, washing, light and rubbing fastness.

Findings

The effect of aftertreating the dyed cotton was found to significantly improve the light and wet rub fastness. The surface morphology of the dyeing remained unaffected as depicted by the absence of any finish residues.

Research limitations/implications

The protective effect of the cation–tannin aftertreatments was examined with a view to providing the necessary commercial performance; however, it was established that the dry rub fastness was either reduced or remained unaffected and the wash fastness to International Organization for Standardization 105 C09 was also marginal.

Originality/value

This finishing technique is novel and can be found useful for manufacturing sulphur-dyed products with the improved light and wet rub fastness.

Details

Pigment & Resin Technology, vol. 49 no. 6
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 28 May 2021

Quratulain Mohtashim, Muriel Rigout and Sheraz Hussain Siddique Hussain Yousfani

Sulphur dyes provide an inexpensive medium to dye cellulosic fibres with heavy shade depths. They offer moderate to good fastness to light and wet treatments. However, owing to…

Abstract

Purpose

Sulphur dyes provide an inexpensive medium to dye cellulosic fibres with heavy shade depths. They offer moderate to good fastness to light and wet treatments. However, owing to the environmental hazard produced by the use of sodium sulphide, the practical implication of these dyes is steadily decreasing. Moreover, these dyes are prone to oxidation causing pronounced fading on exposure to laundering. This paper aims to present the green processing of sulphur dyes by using a biodegradable reducing agent in place of sodium sulphide to dye cotton fabrics. The study also proposes after-treatments with tannin to improve the fastness properties of the dyeings.

Design/methodology/approach

In this study, dyeings were produced on cotton fabric with a range of C.I. Leuco Sulphur dyes, which were reduced with sodium sulphide and glucose. Sulphur dyeings were after-treated with an environment-friendly tannin-based product (Bayprotect CL (BP)); subsequently, the after-treated samples were evaluated for colour strength, wash, light and rubbing fastness.

Findings

A novel after-treatment method was developed, which substantially improved the wash fastness of C.I. Leuco Sulphur Black 1 dyeing to ISO 105 C06/C09 washing. However, the degree of this improvement varied for the other sulphur dyes used. The surface morphology and the possible mechanisms for the improved fastness properties were also discussed.

Research limitations/implications

The effect of after-treatment was significant for improving the wash fastness of sulphur black dyeings in particular, while the effect on other colours was minor. Significant improvements were observed for light and wet rub fastness for most of the dyeings, which signifies the importance of tannins as a finishing agent.

Practical implications

It is observed that the tannin-based product, BP, is found to provide the photoprotective effect by improving the lightfastness of the dyeings. Future research may involve the exploration of various tannins as a finishing agent to sulphur dyeings.

Originality/value

This novel finishing technique is found significant for improving the wash fastness of sulphur black 1 dyeings for both the reducing systems. Improvements were also observed for light and wet rub fastnesses for most of the dyeings.

Details

Pigment & Resin Technology, vol. 51 no. 2
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 14 June 2022

Sheraz Hussain Siddique Hussain Yousfani, Salma Farooq, Quratulain Mohtashim and Hugh Gong

Porosity is one of the most important properties of the textile substrate. It can influence the comfort of a garment by affecting its breathability and thermal conductivity…

Abstract

Purpose

Porosity is one of the most important properties of the textile substrate. It can influence the comfort of a garment by affecting its breathability and thermal conductivity. During the process of dyeing, the dye liquor comes in contact with the substrate; the absorption of the dye liquor into the substrate will be dependent on its porosity. The concept of porosity between the yarns of fabric is a common phenomenon; however, the porosity between the fibres in the yarn can also influence the dyeing behaviour of the fabric.

Design/methodology/approach

In this research, ring and rotor yarns of 25/s and 30/s counts are considered as textile substrates. The porosity of yarns was determined theoretically and experimentally using the image analysis method.

Findings

It was found that theoretical porosity is independent of the yarn manufacturing method. In addition, 30/s yarn was more porous as compared with 25/s yarn having a higher pore area. Rotor yarns had higher porosity, dye fixation and K/S as compared with ring yarns. Dyeing behaviour was also dependent on the count of yarn. Specifically, 30/s yarns have higher dye fixation as compared with 25/s yarns. However, 25/s yarns were dyed with deeper shades showing higher K/S values. Also, 25/s yarns are coarser than 30/s yarns having higher diameters and cross-sectional area, thus resulting in deeper shades and higher K/S values.

Originality/value

This novel technique is based on the comparative study of the porosity of various types of yarns using the image analysis technique. This investigation shows that the porosity between the fibres in the yarn can also influence the dyeing behaviour of the yarn.

Details

Pigment & Resin Technology, vol. 52 no. 6
Type: Research Article
ISSN: 0369-9420

Keywords

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